Selectivity in acetonide formation from a polyol. Ask Question 2 $ begingroup$ In my total synthesis lecture notes the above example is given in which a polyol is reacted under acetonide forming conditions. But these kinds of reactions are usually ran with an excess of the acetone/dimethoxypropane, so its likely to go on as many times as.
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CAS Number:2325-10-2
Molecular Formula:C14H14O2
* Refer to Certificate of Analysis for lot specific data (including water content).
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Chiral reagent. C2 symmetric chiral diol with versatile applications as a chiral auxiliary, building block, and chiral ligand.
References
1. Marshall, J.A. Xie, S. J. Org. Chem. 60, 7230, (1995) 2. Stolle, A. et al. Tetrahedron Lett. 35, 3521, (1994) 3. Burk, M.J. et al. J. Am. Chem. Soc. 115, 10125, (1993) 4. Burk, M.J. et al. Tet. Asym. 2, 569, (1991) 5. Pichon, M. Figadere, B. Tet. Asym. 7, 927, (1996) 6. Matteson, D.S. Man, H.-W. J. Org. Chem. 59, 5734, (1994) 7. Ho, O.C. et al. Organometallics 14, 2855, (1995)
Solid
Store at room temperature
853020
MFCD00064255
C1=CC=C(C=C1)[C@@H]([C@H](C2=CC=CC=C2)O)O
Certificate of Analysis
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